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Cement Energy Storage – Two Ways

Cement Energy Storage – Two Ways

Cement, the binding agent in concrete, is the world’s most widely utilized construction material and may soon be used as cement energy storage. However, emerging research reveals its overlooked potential to serve as a cement energy storage medium in two completely different ways: solid thermal batteries and supercapacitors (when combined with carbon).

Cement Blocks as Thermal Batteries

According to an article in the Journal of Composites Science, scientists have developed a method to produce cement-based blocks that effectively function as thermal batteries. Their technique infuses cement blocks with the ability to soak up renewable electricity when manufactured and then discharge it later on demand as usable heat.

The researchers use chemical alterations during the concrete mixing process to integrate phase change materials into the cement binder matrix. These phase-change materials have the ability to store and release thermal energy.

The resulting cement energy storage blocks contain phase change materials that can absorb electricity when it is most abundant and inexpensive from the grid or renewable sources. The charged blocks can then act as solid thermal batteries, releasing their stored energy as heat when needed for space and water heating systems.

In initial tests, the team achieved energy densities comparable to lithium-ion batteries in their cement energy storage-based blocks. This stored energy is emitted as gentle heat when water is added, with adjustable discharge rates. The blocks can offer long-duration energy storage across daily cycles or entire seasons.

By incorporating waste materials like plastic ash during production, the researchers achieved lower costs than conventional concrete blocks or batteries. Additional waste heat captured during block fabrication can provide self-generated power.

The creators say that scale adoption of such cement energy storage thermal batteries could provide renewable energy storage for buildings while lowering grid demand peaks. The cement blocks offer an alternative to mining metals like lithium, cobalt, and nickel, which are finite and environmentally destructive to extract.

This novel approach redirects one of cement’s existing useful properties – its high thermal mass – towards storing renewable energy rather than fossil fuels traditionally used for heat in cement kilns. It points to one-way cement could aid sustainable energy transitions through material innovation.

 

Conductive Cement-Carbon Composites

Researchers at MIT have also demonstrated cement energy storage’s potential as an energy storage medium by transforming it into a highly efficient supercapacitor. Their method infuses cement with carbon-based additives to create cement-derived composites with enhanced conductive properties.

The MIT team found that the resulting material attained supercapacitor-like behaviors by mixing cement with inexpensive carbon black additives. This was due to carbon black creating a conductive surface area network throughout the composite.

With just 3% carbon black content by volume, cement’s conductivity spiked to levels comparable to powerful supercapacitors. The team states that a cement block around 45 cubic meters in size could potentially store up to 10 kilowatt-hours of energy – equal to an average home’s daily usage.

While still experimental, the researchers say these carbon-infused cement energy storage composites could enable integrated energy storage in concrete structures. Walls, foundations, or roadways made with such cement mixtures might capture solar, wind, or waste energy onsite for later usage.

The carbon provides the charge-storing capacity, while ubiquitous cement allows for scalable, inexpensive production since these composites do not rely on scarce materials like lithium or cobalt. Combined, they offer unique advantages as sustainable energy storage solutions.

 

Conclusion

Together, these two emerging techniques demonstrate that one of the planet’s most abundant building materials – cement – can potentially provide flexible, large-scale energy storage as demands grow.

While still in the early stages, both research trajectories showcase cement’s latent abilities to store energy through novel manufacturing processes and composite ingredients. With further advancement, cement energy storaget-based batteries and supercapacitors may offer new tools for enabling greater renewable energy integration across infrastructure. The present global ubiquity of concrete construction means cement-derived energy storage could be rapidly deployable once perfected. Unlocking the hidden attributes of cement through materials science and engineering may yield key innovations to support grids in an electrified, renewable future.

 

 


 

 

Source   Happy Eco News

New Carbon Capture Tech Turns CO2 into Solid Carbon

New Carbon Capture Tech Turns CO2 into Solid Carbon

New capture technology turns CO2 into solid carbon, a coal-like product that can be safely reburied.

Scientists may have discovered a groundbreaking new method to pull out of the air and convert CO2 into solid carbon flakes. Researchers at Australia’s Royal Melbourne Institute of Technology (RMIT) have pioneered an efficient carbon mineralization process using liquid metal catalysts. This technology could provide a sustainable way to capture atmospheric CO2 and safely store it long-term as a stable solid.

Most carbon capture techniques today focus on compressing CO2 gas into a liquid that is injected deep underground. However potential leakage risks make this method less than ideal for permanently storing billions of tons of carbon dioxide. We urgently need innovative solutions to remove and safely store the CO2 already overburdening our atmosphere.

That’s why RMIT’s new mineralization approach to turn CO2 into solid carbon is so promising. It converts greenhouse gases into inert carbon solids at room temperature. This offers a potentially cheaper, more secure form of carbon storage compared to current methods.

RMIT’s method utilizes molten liquid metals to trigger a chemical reaction, transforming gaseous CO2 into solid carbon flakes. This occurs at ambient temperature inside a simple glass tube device. The process works by sending CO2 into the glass tube containing a liquid metal alloy of gallium, indium, tin, and cerium. Running an electric current through the metal accelerates the carbon mineralization reaction.

Carbon steadily accumulates as a layer of solid flakes on the liquid metal surface and the only byproduct of the process is pure oxygen. The flakes are then removed allowing the process to continue indefinitely. Because this process occurs are room temperature, the energy requirements are far lower than other systems.

The researchers experimented with different metal compositions and temperature conditions to optimize the carbon conversion process. Once optimized, the system can continuously pull in and convert atmospheric CO2 into solid carbon without additional heat or pressure.

Unlike underground injection techniques, solid carbon can easily be collected for safe, permanent storage. The carbon solids could even be processed into materials like carbon fiber. And since the process only needs a small amount of electricity and air, it has minimal environmental impact or manufacturing costs.

Turning CO2 into solid carbon could be a more predictable, sustainable and longer lasting approach to carbon capture and storage. The RMIT team is already investigating ways to scale up the liquid metal carbon mineralization method. Adoption by power plants or heavy industry could significantly cut CO2 outputs.

Finding viable ways to remove excess greenhouse gases is critical to slow global warming. Since the Industrial Revolution, over 1.3 trillion tons of carbon dioxide have entered the atmosphere – and the pace is accelerating. New solutions like RMIT’s carbon mineralization technology will be essential to extracting legacy emissions already dangerously heating our planet.

 


 

 

Source   Happy Eco News

Carbon capture: UK’s first plant could remove 1.5 million tonnes of CO2 from the air a year

Carbon capture: UK’s first plant could remove 1.5 million tonnes of CO2 from the air a year

A huge carbon capture power station has won planning permission for the first time in the UK.

The Keadby 3 plant in north Lincolnshire is the first carbon capture and storage (CCS) project to be greenlit by the government.

The news came the same day as Levelling Up Secretary Michael Gove approved a new coal mine in England – the first in 30 years, which will release an estimated 400,000 tonnes of greenhouse gas emissions (equivalent to 200,000 extra cars on the roads).

Carbon capture technology was part of the justification for allowing a new coal mine – which Gove claimed would be “net zero compliant”. But commentators were quick to point out the as-yet unproven technology is not in commercial use in the UK.

The new CCS project seeks to change that as soon as 2027. It is backed by Britain’s SSE Thermal, part of SSE, and Norwegian energy company Equinor – better known as an oil and gas major.

Grete Tveit, senior vice president for low carbon solutions at Equinor, describes it as “a significant milestone for our joint ambition to deliver clean, flexible and efficient power to support intermittent renewable generation and maintain security of supply.”

Business and Energy Secretary Grant Shapps signed off the proposed plant following extensive consultation, SSE said in a statement on its website on Thursday.

Keadby 3 would have a generating capacity of up to 910 megawatt (MW) and capture up to 1.5 million tonnes of CO2 a year, according to SSE. It says this represents at least 5 per cent of the UK government’s 2030 target.

It will be situated next to Keadby 1 and 2; two gas fired power stations in northern England’s Humber region.

The plan is for carbon pulled from the air to be sent through CO2 pipelines being built to transport emissions from industrial plants across the Humber to storage under the North Sea.

This is subject to final approval and investment; though the plant got a development consent order, the project is still in the due diligence stage of the government’s ‘cluster sequencing process’ for CCS.

Advocates of the technology say it has a key role to play in decarbonising the grid. But using CCS alongside gas fired power stations remains controversial among green groups.

“It is perverse that the world’s biggest polluters are in fact using CCS to extract more fossil fuels, creating more emissions,” Ken Penton, climate campaigner at Global Witness previously told Euronews Green.

“The time has now come for governments to stop chasing the CCS unicorn and instead build vibrant renewable energy sectors and massively increase energy efficiency of homes and businesses. The best and most proven way to stop climate change is to keep fossil fuels in the ground.”

 

 


 

 

Source euronews.green

Could Paint Really Be A Solution For Carbon Capture?

Could Paint Really Be A Solution For Carbon Capture?

A college graduate by the name of Kukbong Kim has come up with an incredible new formula for indoor and outdoor paint made of recycled concrete. The amazing thing about this new paint is that it actually has two major benefits for the environment.

Firstly, it uses discarded concrete from the construction industry, which otherwise would end up at a landfill site. This has negative effects on soil pH levels, making them a lot more alkaline and limiting the ability to reclaim landfill sites.

Secondly, the paint is capable of absorbing up to 20% of its weight in CO2. Now imagine if this kind of paint made it onto all the walls and how much that could impact atmospheric CO2 levels.

DeZeen has reported some interesting facts about carbon capture capabilities.

“Cement is the most carbon-intensive ingredient in concrete and is responsible for eight per cent of global emissions. But when concrete is recycled, only the aggregate is reused while the cement binder is pulverised to create waste concrete powder and sent to landfill, where it can disturb the pH balance of the surrounding soil.”

And here’s the interesting thing about this story. If a college graduate can come up with such an idea for paint, what other construction and household materials could be coming our way that will achieve the same thing?

 


 

Source Greencitizen 

European Investment Bank supports thermal, gravity energy storage projects

European Investment Bank supports thermal, gravity energy storage projects

The EU’s European Investment Bank has pledged support for a long-duration thermal energy storage project and a gravity-based energy storage demonstration project.

They have been selected among 15 projects defined as large-scale — each requiring capital costs of more than €7.5 million (US$8.5 million) — through EU Innovation Fund grants for Project Development Assistance (PDA), administered by the bank.

A total of 311 applications were received for clean energy or decarbonisation projects after the call for submissions opened last summer.

Of these, seven were selected to receive direct funding from a €1.1 billion budget and include hydrogen, carbon capture and storage, advanced solar cell manufacturing and other technologies.

The 15 among which the two energy storage projects were selected will receive PDA, technical assistance for various stages of their development.

The other 13 projects cover technologies including wind propulsion for cruise ships, hydrogen fuel cells for marine vessels, green methanol production, greenhouse gas (GHG) and carbon capture and storage, bioethanol, power-to-liquid for aviation fuels and other areas.

There is also an electric vehicle (EV) battery project, which will use ultra-pure electrolyte salt to improve lithium-ion batteries and a project to develop and upscale the synthesis of curved graphene and electrode production technologies.

 

Thermal energy storage project Sun2Store

Sun2Store, a 100MW/1,000MWh thermal energy storage project in Spain was selected for a PDA agreement. Using technology developed by US startup Malta Inc, the project will enable 10-hour duration storage of energy.

Malta Inc has developed a technology it calls ‘pumped heat’ electricity storage, which could provide up to 200 hours of storage, although the company is largely targeting 10 – 12 hour applications. It converts electricity to heat, which is then stored in molten salt. Simultaneously, the system produces cold energy stored in special vats of an anti-freeze-like cooling liquid.

The hot and cold energy are then converted back into electricity as required, using a temperature difference-driven heat engine. The company has raised funds from investors including Bill Gates’ Breakthrough Energy Ventures and is one of the founding members of the international Long Duration Energy Storage Council.

It has deals in place with equipment manufacturers Bechtel and Siemens Energy for co-development and supply of key components.

Funds have been granted to Malta Inc’s European affiliate company, Malta Iberia Pumped Heat Electricity Storage (Malta Iberia). The EIB will provide technical assistance to Malta Iberia, including an independent technology assessment, which will verify the storage facility’s key technical parameters.

Malta Inc recently announced plans for a similar-sized project in Canada.

 

Gravity storage project GraviSTORE

Scotland-headquartered startup Gravitricity was the other energy storage system industry recipient of a PDA agreement through the Innovation Fund.

The EIB will support Gravitricity’s plans to build a full scale 4-8MW project in a former mine shaft.

Located in mainland Europe, the project follows a 250kW demonstrator which operated in Scotland’s capital city Edinburgh throughout the summer and for which specialists appointed by the EIB have begun evaluating test results.

The results of the Edinburgh demonstrator are to be combined with a review of local revenue streams to produce a commercial risk assessment that will inform detailed design and development activities.

“We already have a high level of confidence in our technology and its ability to store energy effectively. What these studies will bring is increased understanding and confidence in how a full-scale project will play into a specific energy market,” said Chris Yendell, project development manager at Gravitricity.

Gravitricity’s energy storage solution works by raising weights in a deep shaft, with disused mine shafts currently being targeted by the firm, and releasing them when energy is required. Its proposed single weight full scale system could deliver up to 2MWh of energy storage, with future multi-weight systems having the potential for a capacity of 25MWh or more.

Alongside the test evaluations, the EIB has now also committed 120 days of consultancy time to advance the full scale project.

In October, Gravitricity engineers visited the recently mothballed Staříč mine in the Moravian Silesian Region of Czechia to investigate its potential for the project. The Gravitricity team is to head to mainland Europe later in January to further evaluate their shortlist, with a final selection decision expected within the next few months.

The firm is also exploring opportunities for a purpose-built prototype shaft at a brownfield location in the UK, where gravity storage could be combined with hydrogen and inter-seasonal heat storage.

Gravitricity story by Alice Grundy.

 


 

Source Energy Storage News

‘Just a new fossil fuel industry’: Australia to send first shipment of liquefied hydrogen to Japan

‘Just a new fossil fuel industry’: Australia to send first shipment of liquefied hydrogen to Japan

Australia will export its first load of liquefied hydrogen made from coal in an engineering milestone which researchers say could also lock in a new fossil fuel industry and increase the country’s carbon emissions.

Under the $500m Hydrogen Energy Supply Chain (HESC) pilot project, hydrogen will be made in Victoria’s LaTrobe valley from brown coal and transported aboard a purpose-built ship to Japan, where it will be burned in coal-fired power plants.

Carbon capture and storage will be used in an attempt to reduce the carbon emissions associated with making the hydrogen and supercooling the gas until it forms a liquid before it is loaded aboard the Suiso Frontier vessel. The first shipment is due to depart from Hastings in the coming days.

The project is being led by a Japanese-Australian consortium including Japan’s J-Power, Kawasaki Heavy Industries, Shell and AGL.

The prime minister, Scott Morrison, said on Friday the development was a “world-first that would make Australia a global leader” in the budding industry.

“A successful Australian hydrogen industry means lower emissions, greater energy production and more local jobs,” Morrison said in a statement.

“The HESC project puts Australia at the forefront of the global energy transition to lower emissions through clean hydrogen, which is a fuel of the future.”

Morrison also announced an additional $7.5m to support the next stage of the project, which has a goal of producing 225,000 tonnes of carbon-neutral hydrogen each year and an additional $20m towards the next stage of the CarbonNet project which aims to produce commercial-scale carbon capture and storage.

According to government estimates, this will reduce emissions by 1.8m tonnes a year.

But Tim Baxter, a senior researcher for climate solutions at the Climate Council, said the assumptions were questionable as the reliance on “fossil hydrogen” meant government needed to “come back with a zero emissions hydrogen plan”.

“Hydrogen derived from fossil fuel sources, like what is being shipped out of the LaTrobe Valley, which is derived from some of the world’s dirtiest coal, is really just a new fossil fuel industry,” Baxter said.

“Fossil hydrogen is a whole new fossil fuel industry, regardless of whether carbon capture and storage is attached to it. It results in extraordinary greenhouse gas emissions. It’s not a climate solution.”

Though “clean hydrogen” has become central to the government’s emissions reductions plans, hydrogen produced by fossil fuels is more expensive, will release more greenhouse gas emissions and comes with greater risk of creating stranded assets.

 

Dr Fiona Beck, an engineer with the ANU Institute for Climate, Energy and Disaster Solutions, said Friday’s announcement did mark an engineering milestone as it showed it was technically possible to liquefy and store hydrogen for transport, as this was more difficult to do than with LNG.

However, Beck, a co-author of a recent peer-reviewed paper published in the Journal of Cleaner Production that examined the emissions that will be created out of the proposed Japanese-Australia hydrogen supply chain, said if hydrogen made with fossil fuels became the norm, Japan would be transferring its emissions to Australia.

Japan, which has limited options for onshore wind projects, has been looking for ways to reduce its CO2 emissions. One way is by burning ammonia, which is made with hydrogen, in its coal-fired power plants – which are also powered with Australian coal.

Under current CO2 accounting standards by which emissions are measured, Japan would slash its emissions while shifting them across to Australia owing to the CO2 emissions involved in creating, processing, transporting and shipping the hydrogen.

“If you’re importing hydrogen made from coal, essentially the emissions are going to be worse in Australia rather than it would be by just taking that coal and burning it in Japan,” Beck said.

“There’s no policy pressure or economic reason why Japan would buy low-emissions hydrogen when it gets the same benefit by buying cheap, high-emissions hydrogen.”

Beck said that while current government planning stated its intention to reduce emissions associated with creating hydrogen “there’s very few actual mechanisms to do this”.

“Unless Australia has some strong policy to keep its carbon emissions down, we could see a rise in emissions in Australia due to this hydrogen trade.”

 


 

Source The Guardian

Building’s hard problem – making concrete green

Building’s hard problem – making concrete green

A time-travelling Victorian stumbling upon a modern building site could largely get right to work, says Chris Thompson, managing director of Citu, which specialises in building low-carbon homes.

That’s because many of the materials and tools would be familiar to him.

The Victorian builder would certainly recognise concrete, which has been around for a long time.

The world’s largest unreinforced concrete dome remains the one at Rome’s Pantheon, which is almost 2,000 years old. The Colosseum is largely concrete too.

Today we use more concrete than any substance, other than water.

That means it accounts for about 8% of the carbon dioxide (CO2) we emit into the atmosphere. That is substantially more than the aviation industry, which makes up about 2.5% of emissions.

 

GETTY IMAGES
The Pantheon in Rome – almost 2,000 years old and built from concrete. GETTY IMAGES

But some companies are developing concrete that has a much lower CO2 impact.

Citu is building its headquarters in Leeds from a new low-carbon concrete that it says cuts CO2 emissions by 50% compared to traditional concrete.

It has used 70 cubic metres of it for the building’s foundations.

 

Some buildings, like this one in Mexico, are being constructed using Cemex’s low-carbon concrete. CEMEX

 

This concrete, released last year by Mexico’s Cemex under the label Vertua, is one of a series of recent developments helping pave the way to greener concrete.

Making cement, which makes up 10-15% of concrete, is a carbon-intensive process. Limestone has to be heated to 1,450C, which normally requires energy from fossil fuels and accounts for 40% of concrete’s CO2.

This separates calcium oxide (which you want) from carbon dioxide (which is the problem).

This calcium oxide reacts further to form cement. Grind some into powder, add some sand, gravel and water, and it forms interlocking crystals.

Voilà, concrete.

So how can you do all this without releasing so much CO2?

 

Karen Scrivener has been working on a way to replace some of the cement in concrete. EPFL

 

One way is by replacing much of the conventional cement with heated clay and unburnt limestone, says Karen Scrivener, a British academic and head of the construction materials laboratory at Switzerland’s Ecole Polytechnique Fédérale de Lausanne.

For a long time, people (think, Romans) knew you could substitute some of the cement with ash from burning coal (or volcanoes). Or more recently, slag from blast furnaces. This even improved concrete’s strength and durability.

Prof Scrivener was approached by Prof Fernando Martirena from Cuba, who thought it might be possible to use clay in the production of concrete.

So together they worked out a way to replace a really big chunk of conventional cement, and produce equally strong concrete.

Not only would that mean 40% less CO2, it also works with existing equipment, according to Prof Scrivener.

And that’s crucial for a material that has to be competitively priced.

Two companies last year began commercially cooking up this product, called LC3 (for limestone calcined clay cement).

“I reckon next year about 10 plants are going into operation, and really we can see an exponential take-off after that,” she says.

A further 10-20% savings on CO2 emissions can come from finding new ways of making cement more reactive, she adds.

Often people pour in more cement than they actually need, to get early strength.

But if you put in very tiny amounts of other minerals instead, that seems to increase the reactivity too, she says.

Another approach is just coming up with an utterly different way to clench the sand and stone particles together, without cooking limestone into calcium oxide.

This is what Vertua does, says Davide Zampini, head of research for Cemex, the world’s second biggest building materials business.

“It’s a binder that’s rich in aluminosilicates (minerals made from aluminium and silicon), and we have produced chemicals to activate those, and go through a reaction called geopolymerisation,” he explains.

This forms a 3D network of molecules, and a solid binder to grip sand and stone in place.

But it’s not as cheap as conventional concrete, admits Dr Zampini.

You have to find a customer who is really keen on significantly reducing the CO2 footprint of their buildings, he says, like Citu in Leeds.

 

Cement firms are experimenting with towers like this one which catch the CO2. LEILAC

 

A third approach is using a big steel tube, says Daniel Rennie, co-ordinator of a project called LEILAC (Low Emissions Intensity Lime and Cement).

It’s 60m (197ft) tall. You can add it to an existing cement plant.

You “chuck materials down from the top” and it gently floats down the tube, which is heated from the outside.

As CO2 comes off the particles, “we just capture it at the top, the calcium oxide continues to the bottom and continues its journey in the cement-making process,” he says.

The project is run by Calix, an Australian company that makes environmentally sustainable technology for industry.

 

Once captured by the tower the CO2 is compressed and stored in an empty oil reservoir. LEILAC

 

The company had been thinking about how to decarbonise another building material.

“And just, the penny dropped, and we could apply this to cement,” Mr Rennie says.

A little pilot tower, built in 2019, is now accounting for 5% of production at Heidelberg Cement’s Lixhe plant in Belgium.

This is capturing about 25,000 tonnes a year of CO2.

In Germany, they’re building one at another Heidelberg plant in Hanover, where 20% of total production will go through the new process, capturing about 100,000 tonnes of CO2 a year.

Once captured, the CO2 is compressed, shipped in a barge to Norway, and stored in an empty oil reservoir under the North Sea.

Normally “90% of the cost is capturing the carbon”, so this just leaves the cost of transport and storage.

 

Innovations that were just ideas 20 years ago are now taking hold in the concrete industry, says Claude Loréa. JOHNNY BLACK

 

“I’ve been in this industry 20 years, and I really see a big change,” says Claude Loréa, cement director from the Global Cement and Concrete Association.

“Stuff we dreamed about 20 years ago is now coming through,” she adds.

And cement makers have already reduced their carbon emissions “almost by 20% since 1990”, she says, largely by making kilns more energy-efficient.

Still, while we can probably get overall CO2 emissions down by 60-80%, we’ll still end up with some we’ll need to capture and store, says Prof Scrivener.

Also, there’s no point looking for intricate solutions that can just be used in “some very sophisticated factories in the US”, she says.

Around 90% of future cement production will take place outside the wealthy OECD countries.

A concrete path to cutting concrete’s carbon emissions needs alternatives that will work well and cheaply for the coming building booms in India and Africa.

Concrete may have been born in Rome and Britain.

But China made more concrete between 2011 and 2013 than the US did in the whole 20th Century.

 


 

By Padraig Belton – Technology of Business reporter

Source BBC