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A very Finnish thing’: Big sand battery to store wind and solar energy using crushed soapstone

A very Finnish thing’: Big sand battery to store wind and solar energy using crushed soapstone

The battery will be able to store a week’s heat demand in winter – how does it work?

A huge sand battery is set to slash the carbon emissions of a Finnish town.

The industrial-scale storage unit in Pornainen, southern Finland, will be the world’s biggest sand battery when it comes online within a year.

Capable of storing 100 MWh of thermal energy from solar and wind sources, it will enable residents to eliminate oil from their district heating network, helping to cut emissions by nearly 70 percent.

“It’s exciting to build a large-scale thermal energy storage, which will also act as a primary production plant in Pornainen’s district heating network,” says Liisa Naskali, COO at Polar Night Energy, the company behind the innovation.

“This is a significant step in scaling up the sand battery technology.”

 

Sand batteries are getting bigger in Finland

The new 1 MW sand battery has a precursor. In May 2022, Polar Night Energy rigged a smaller design to a power station in Kankaanpää town.

Launched just as Russia cut off gas supplies in retaliation for Finland joining NATO, the project was a timely example of how renewable energy could be harnessed in a new way.

Euronews Green previously spoke to the young Finnish founders, Tommi Eronen and Markku Ylönen, who engineered the technology.

“We were talking about how – if we had the liberty to design a community for ourselves – how could we solve the energy problem in such a confined environment?” Markku said of the inspiration behind Polar Night Energy in 2018.

“Then quite quickly, especially here in the north, you run into the problem of energy storage if you’re trying to produce the energy as cleanly as possible.”

The friends started playing around with ideas, landing on sand as an affordable way to store the plentiful electricity generated when the sun is shining, or the wind blowing at a high rate.

Finding a way to store these variable renewables is the crux of unleashing their full potential. Lithium batteries work well for specific applications, explains Markku, but aside from their environmental issues and expense, they cannot take in a huge amount of energy.

Grains of sand, it turns out, are surprisingly roomy when it comes to energy storage.

The sand battery in Pornainen will be around 10 times larger than the one still in operation at Vatajankoski power plant in Kankaanpää. The start-up also previously connected a pilot plant to the district heating network of Tampere city.

 

So how do sand batteries work exactly?

It’s quite a simple structure to begin with, Polar Night Energy said of its prototype. A tall tower is filled with low-grade sand and charged up with the heat from excess solar and wind electricity.

This works by a process called resistive heating, whereby heat is generated through the friction created when an electrical current passes through any material that is not a superconductor. The hot air is then circulated in the container through a heat exchanger.

The sand can store heat at around 500C for several days to even months, providing a valuable store of cheaper energy during the winter. When needed, the battery discharges the hot air – warming water in the district heating network. Homes, offices and even the local swimming pool all benefit in Kankaanpää, for example.

“There’s really nothing fancy there,” Markku says of the storage. “The complex part happens on the computer; we need to know how the energy, or heat, moves inside the storage, so that we know all the time how much is available and at what rate we can discharge and charge.”

 

How will the sand battery serve residents in Pornainen?

Having refined its charging algorithms, Polar Night Energy is now ready to scale up the storage tech in Pornainen.

Once completed, the new battery will be integrated with the network of Loviisan Lämpö, the Finnish heating company that supplies district heating in the area.

“Loviisan Lämpö is moving towards more environmentally friendly energy production. With the Sand Battery, we can significantly reduce energy produced by combustion and completely eliminate the use of oil,” says CEO Mikko Paajanen.

The project also aligns with Pornainen’s plans for carbon neutrality. Many of its buildings, including the comprehensive school, town hall, and library, rely on district heating.

Mayor of Pornainen Antti Kuusela says the municipality “welcomes all innovative development projects that reduce emissions in district heating operations and contribute to network expansion.”

In total, the sand battery is expected to knock off 160 tonnes of carbon dioxide equivalent emissions per year. As well as weaning the town off oil, woodchip burning is expected to drop by 60 per cent as a result.

The battery’s thermal energy storage capacity equates to almost one month’s heat demand in summer and a one-week demand in winter in Pornainen, Polar Night Energy says.

Construction and testing of the 13 metres high by 15 metres wide battery is estimated to take around 13 months, meaning it should be keeping residents warm well before winter 2025.

 

Is sand a sustainable material?

“We wanted to find something that can be sourced nearly everywhere in the world,” Markku said. But is sand as ubiquitous as we might think?

Demand for the construction material is set to soar by 45 per cent in the next 40 years, according to a recent Dutch study. Building sand is typically extracted from rivers and lakes, and ‘sand pirates’ are speeding up its loss from these ecosystems.

But as far as the Finnish engineers are concerned, it doesn’t really matter where the sand comes from. Though builders’ sand was used initially (to limit transport emissions), sand batteries work with any sand-like material that has a high enough density, within certain thermodynamic parameters.

In Pornainen, Polar Night Energy has found a sustainable material in crushed soapstone; a by-product of a Finnish company’s manufacture of heat-retaining fireplaces.

“Tulikivi is a well-known and traditional company,” says Naskali. “The soapstone they use is a very Finnish thing.”

“We always choose the thermal energy storage medium based on the customer’s needs. Examining and testing different materials is crucial for us to use materials that are suitable in terms of properties, cost-effectiveness, and promotion of circular economy,” she adds.

Polar Night Energy has big ambitions to take its technology worldwide.

As Markku told us back in 2022, “we want to build a hundred times larger storages around the world as fast as possible.”

 

 


 

 

Source  euronews.green

Water Based Battery Safer than Lithium

Water Based Battery Safer than Lithium

A novel water based battery is said to be safer than lithium at half the cost.
A Boston-area startup called Alsym Energy has introduced a rechargeable water based battery that could match lithium-ion batteries’ performance at a fraction of the price.

In addition to using inexpensive, easily accessible materials like manganese and metal oxide, the novel battery is based on water, according to an initial report from Fast Company.

Being a water based battery means it avoids some of the main drawbacks of current batteries, such as the potential for lithium-ion battery fires and the negative impact of mining on the environment. And thanks to the use of non-toxic materials, the water based battery design is simpler to recycle, which is always a bonus.

Electric vehicles are becoming more important as the world’s nations step up their efforts to decarbonize the grid. That’s because they can aid in decarbonizing both transportation and supply of electricity through reduced tailpipe emissions and offer flexibility. Naturally, many automakers are tapping into the market by producing luxurious EVs; however, the expensive price tag remains to be a problem to this day. The costs are partly due to the lithium-ion batteries that are used in electric vehicles, which are too costly to make EVs that can compete in price tag with cars that run on fossil fuels.

This is where Alsym Energy, which recently emerged from stealth and secured $32 million from investors, comes in. According to a press release, with its first partner being an automaker in India, the startup wants to make it possible for manufacturers to produce cheaper electric vehicles.

“Our motivation was to make it affordable so that it could be widely deployed as opposed to niche,” Mukesh Chatter, CEO and co-founder of the startup, told Fast Company.

The Alsym Energy water based battery is inexpensive enough that it might be used in developing countries to store off-grid solar power. This is especially crucial for individuals who do not currently have access to energy.

 

What Makes the Water Based Battery Special?
The water based zinc battery makes use of other affordable, easily accessible components like manganese and metal oxide. Crucially, it does not contain cobalt, an expensive critical component of lithium batteries that also contributes to supply-chain health and environmental issues due to unethical mining practices. It also doesn’t use lithium at all, which requires resource-intensive salar brine extraction methods, mainly concentrated in conflict-prone regions of South America. Avoiding lithium and cobalt reliance is incredibly important as both metals have seen extreme price increases recently amid surging EV demand.

Lithium carbonate prices have skyrocketed over 750% in the last two years. And cobalt more than doubled in cost since 2020. These unstable dynamics will likely drive up prices of lithium-ion batteries for the foreseeable future. By swapping water for expensive, ethically fraught raw materials, the aqueous zinc batter stands to radically transform the energy storage calculus in terms of affordability, local manufacturing potential, and stability of supply chains.

According to the team behind Alsym Energy, the new design has “lithium-like performance.” But unlike the latter, Alsym Energy’s batteries are not flammable. This saves money as it doesn’t require special protection to avoid fires and gives the batteries additional applications, such as use in ships, where the industry is particularly concerned about fire risk.

If all goes to plan, Alsym Energy will start beta testing with its first customers in early 2023, with high-volume production beginning as early as 2025. The novel battery design will surely make waves globally; however, the company’s priority is to first make it affordable in low-income regions.

 

 


 

 

Source  Happy Eco News

Phosphazene-based electrolytes for high-voltage lithium batteries that work in extreme environments

Phosphazene-based electrolytes for high-voltage lithium batteries that work in extreme environments

Lithium metal batteries have numerous notable advantages over other existing battery systems, including high energy density. Nonetheless, the use of most existing high-energy lithium metal batteries in extreme environments is typically deemed unsafe or unfeasible, due to the volatility and flammability of their electrolytes.

Researchers at Bar-Ila University, University of Technology Sydney, CIC energiGUNE, and Tsinghua University recently set out to develop new electrolytes that could support the safe and stable operation of lithium metal batteries in a broader range of environmental conditions. These electrolytes, introduced in Nature Energy, were synthesized by using the fireproof phosphazene-derivative polymeric matrices.

“Replacing the graphitic anodes with metallic Li is considered a viable path to further increase the energy density of Lithium batteries,” Professor Doron Aurbach, one of the researchers who carried out the study, told Tech Xplore.

“However, the growth of dendrites on Li anode during cycling triggers catastrophic safety hazards, which severely hinders their practical applications. To solve this issue, ether-based electrolytes have been widely employed in Li metal batteries because of their relatively low reactivity with Li metal.”

Ether-based electrolyte solutions have a low viscosity and high ionic conductivity. These favorable properties can facilitate the rapid conduction of Li-ions and the exchange of interfacial charges in lithium batteries.

Ether-based electrolytes are also highly compatible with Li metal anodes, thus they can suppress the growth of dendrites while batteries are charging. Despite these advantages, many ether solvents are highly flammable, thus their use can greatly reduce the safety of battery cells.

“The low boiling points of ethers pose safety risks including fire, explosion, and liquid leakage,” Doron said. “Besides, the insufficient oxidation stability of ether-based electrolytes may lead to uncontrollable solvent decomposition on the cathode surface at high voltage (>4 V vs. Li/Li+), greatly deteriorating the cyclability of high-voltage Li metal batteries.”

In recent years, some research teams also introduced localized high-concentration electrolytes, which limit free solvent molecules in Li+ solvation structures. While these alternative electrolytes can reduce the time it takes to extinguish any fires that might arise, they do not fully eliminate the risk of fires or leakages.

“Polyphosphazene flame retardants with excellent flame-retardant effects have been widely used in the field of polymer flame retardants,” Doron said. “Combined with localized high-concentration electrolytes, the hybrids of polyphosphazene can effectively improve the flame-retardant effect with low addition contents. And the safety of the full cells can be largely promoted.”

In their recent paper, Professor Guoxiu Wang and their colleagues introduced a new versatile strategy to optimize ether-based electrolytes, preventing them from catching fire or leaking while also improving their compatibility with electrodes. This strategy entails a co-solvent and gelation treatment using butenoxycyclotriphosphazene (BCPN) monomers.

“To solve the inherent disadvantages of flammability and poor oxidation stability for ether-based electrolyte, fluoromethyl 1,1,1,3,3,3-hexafluoroisopropyl ether (SFE) was introduced as a co-solvent (served as an anti-solvent) with an ether solvent to improve the oxidation resistance and cathodes’ stability,” Wang said. “Then, these binary electrolytes were gelled in situ by polymerization of BCPN monomers to achieve flame retardancy and interfacial compatibility.”

In initial tests, Wang and his collaborator Dr. Dong Zhou found that their proposed treatment using fluorinated co-solvent and fireproof polymetric matrices fully eliminated risks of fire and electrolyte leakage in lithium metal batteries. The team were also able to achieve electrolytes that are highly compatible with high-energy cathodes using a carefully designed Li+ solvation sheath, along with the BCPN-derived protective surface films formed on the cathodes.

“We manufactured high-energy-density Li||NCM811 batteries using our gel electrolyte and these batteries achieved high-capacity retention, superior low-temperature performance, good cyclability under high pressure and steady power supply under abusive conditions,” Dr. Dong Zhou said. “We successfully solved the safety problem for high-energy lithium metal batteries.”

The recent work by this team of researchers could have important implications for the development of next-generation lithium batteries. The electrolytes introduced in Nature Energy and their underpinning design strategy could soon open a new path for fabricating high energy, durable and safely rechargeable Li metal batteries that can operate in extreme environments.

“In our next studies, we intend to continue our research on improving battery safety and low temperature performance, which would help to expand the extreme environment application of high energy density batteries, for instance allowing their integration in aerospace vehicles, submarines and polar region devices,” Wang added.

 

 


 

 

Source  Tech Xplore