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Table Salt in Plastic Recycling

Table Salt in Plastic Recycling

As far back as 6050 BC, salt has been used for various purposes, including religious offerings and valuable trades. The word “salary” was derived from the word salt because it was highly valued, and production was legally restricted in ancient times, so it was historically used as a method of trade and currency.

Table salt is an important and inexpensive kitchen staple today and is used for various uses, including seasoning, food preservation, food texture, cleaning,  and boiling water. We even use salt in healthcare (such as for cleaning wounds) and for deicing roads and sidewalks. But now table salt is entering a new domain: plastic recycling.

Researchers from Michigan State University are proving that salt in plastic recycling has the properties to outperform much more expensive materials that are being explored to help recycle plastics. The MSU team uses pyrolysis to break down the plastics into a mixture of simpler carbon-based compounds, including gas, liquid oil, and solid wax. Pyrolysis is the process of heating an organic material in the absence of oxygen.

One of the challenges of plastic recycling has always been an undesirable wax byproduct, which accounts for over half of the pyrolysis output. The wax obtained from the pyrolysis of waste plastic is generally regarded as a low-value product that requires further treatment in a refinery for it to be considered valuable as chemicals, diesel, petroleum, and gasoline.

Salt in plastic recycling is used as a catalyst to pyrolyze polyolefins (the family of thermoplastics that include polyethylene and polypropylene); the MSU team produced mostly liquid oil that contains hydrocarbon molecules similar to what is found in diesel fuel, which is not suitable for producing new polymers. There was no undesirable wax; over 50% is generally seen when platinum on carbon or aluminum is used as a catalyst. In this experiment, the result was 86% liquid form and 14% gas.

Using salt in plastic recycling as a catalyst also means the salt can be reused simply by washing the liquid oil with water. The team also found that table salt helped in the pyrolisis of metalized plastic films commonly used in food packaging, such as potato chip bags, which currently aren’t being recycled.

Because table salt is relatively inexpensive, using salt in plastic recycling could drastically reduce the costs associated with these processes. The researchers found that table salt can offer a transformative approach toward an inexpensive (4 cents per kg) and efficient pyrolysis methodology for converting mixed plastics waste to useful hydrocarbon products.

The use of table salt in plastic recycling is a relatively new phenomenon. Traditionally, salt has not been used directly in plastic recycling processes. It has been used indirectly in cleaning and preparing plastic items. It can be used as an abrasive agent to help scrub any residues. It is also used to scrub off adhesive labels from plastic containers.

In recycling facilities, electrostatic separation processes are used to separate different types of plastic based on their electrostatic charges. Salt can affect the conductivity of plastics and help in the separation. Furthermore, the traditional recycling process typically involves mechanical methods such as shredding, melting, and extruding rather than chemical reactions that involve salt. This study can drastically change the way plastic is recycled.

The salt in plastic recycling study from Michigan State University is still in its initial phases. Still, if it catches on, it could be an important movement towards how we recycle plastics and can result in more plastic being recycled and repurposed. It’s fascinating that something so simple and abundant, like table salt, can be used to help tackle one of the world’s most pressing issues.

 

 


 

 

Source   Happy Eco News

Novel tech to recycle silver, aluminum from end-of-life solar panels

Novel tech to recycle silver, aluminum from end-of-life solar panels

Scientists from the University of Leicester in the UK have discovered a process to recover silver and aluminum from used PV cells that is cheaper and more environmentally friendly than current recycling processes using mineral acids.

The researchers used the technology on crystalline solar cells measuring 12 × 15 cm, weighing 2 g, and consisting of a 100 µm thick silicon wafer, coated with a 100 nm thick silicon nitride anti-reflective layer on the front side and a 20 µm thick layer of aluminum on the back side, both stripped with silver electrodes approximately 30 μm high.

“First, we place the solar cell in an aluminum chloride solution. The aluminum electrode is removed from the silicon wafer. We use ultrasound to promote the dissolution of the aluminum, which takes place within a few minutes,” researcher Guillaume Zante told pv magazine.

Given the low cost of aluminum, there may be no economic interest in recovering it, but the aluminum salt solution could be used for wastewater treatment purposes, according to the scientists. “In the second step, the silver is dissolved from the solar cell using iron chloride, an oxidizing agent, in a choline chloride or calcium chloride brine, which takes around 10 minutes,” Zante explained, noting that the components of these two brines, or salt water, are found in chicken feed and grit used on roads to avoid ice, respectively, and are thus widely available, cheap, and low on toxicity.

“It is interesting to note that iron dissolved in water cannot oxidize silver, but iron dissolved in the brine can. Using a brine instead of water improves the ability of iron to oxidize silver and improves the solubility of silver in the brine,” Zante said. “This is due to the presence of chloride ions in the brine. The addition of water to the brine dilutes the chloride ions, allowing the silver chloride to precipitate. Silver chloride is easily filtered from the solution.”

 

 

This process successfully recovers silver chloride with a purity of 98%, which according to the researchers could be converted into metallic silver in a further step, thereby increasing its purity. The process does not affect the silicon wafer and nitride anti-reflective coating, leaving open the possibility to reuse the silicon in PV panels or processing it for other uses.

The results were obtained in a lab setting, using a few grams of solar cells, and may differ at an industrial scale. However, the authors believe that industrialization is feasible due to their use of cheap, low-toxicity and readily available chemicals. “Since we are using cheap chemicals, the price could be as low as the processing costs with mineral acids and in some cases cheaper, around $0.4 lower per kilogram of solar cell as compared to mineral acids,” Zante affirmed.

They presented their findings in “Efficient recycling of metals from solar cells using catalytic etchants,” which was recently published in the Journal of Cleaner Production. The scientists are currently developing a strategy to scale up the technology and to extract other metals from waste sources, including bismuth, tellurium and copper from thermoelectric materials, which are used in perovskite, thin film, and wiring and cabling in solar cells, respectively. They are also attempting to extract gold, nickel and copper from printed circuit-boards, as well as neodymium and dysprosium from waste magnets. The academics are part of the Met4Tech project, which supports the creation of a circular economy for technology metals.

 


 

Source – pv magazines

Scientists from A*Star, NTU find way to upcycle old solar panels

Scientists from A*Star, NTU find way to upcycle old solar panels

Recycling old solar panels is challenging, but scientists from Singapore have found a way to upcycle the silicon inside and turn them into materials that can convert heat into electricity.

The team comprising researchers from the Agency for Science, Technology and Research (A*Star) and Nanyang Technological University (NTU) turned old solar panels into thermoelectric materials.

Such materials convert heat into electricity, and work in a similar way to how hydropower generation plants use water movement to drive turbines to generate electricity.

The joint study was published in the scientific journal Advanced Materials in March.

Dr Ady Suwardi, the deputy head of the soft materials research department at A*Star’s Institute of Materials Research and Engineering said that by moving heat from one side to another, thermoelectric materials generate electricity.

This can then be used for applications like cooling, added Dr Ady, who co-led the study.

The team found that impurities and defects in the silicon used to make solar cells actually enhance the performance of thermoelectric materials.

A solar panel is made up of many solar cells, also known as photovoltaic cells.

Separating the materials used to make solar panels and recycling each of them is a complex and costly process, said Associate Professor Nripan Mathews.

 

The team comprising researchers from A*Star and NTU turned old solar panels into thermoelectric materials. PHOTO: A*STAR

 

Prof Mathews, who is the cluster director of renewables and low-carbon generation (solar) at the Energy Research Institute @NTU (ERI@N), added that current recycling methods are able to recover only the glass and metallic support structures from solar panels.

Solar cells contain a complex mix of materials such as aluminium, copper, silver, lead, plastic and silicon.

Silicon, which is extremely pure, makes up 90 per cent of solar cells. However, this normally ends up in landfills.

This is because silicon has to be chemically treated and remelted to be recycled into pure silicon, said Prof Mathews.

He added that it is challenging, energy-intensive and expensive to recover the silicon to create new, functional solar cells.

“While silicon holds very little weight in the entire solar panel, it is the most valuable part of it, which explains why it is important for us to try and upcycle it,” said Prof Mathews.

 

Upcycling of solar panels (bottom) into valuable heat-harvesting electricity materials such as thermoelectric modules (top). PHOTO: A*STAR

 

The team is currently looking to pilot the technology for large-scale upcycling of waste silicon to create silicon-based thermoelectrics.

This can be used for high-temperature energy harvesting applications such as converting heat generated from industrial waste processes into electricity.

There are a number of research efforts ongoing in Singapore to see how solar panels can be recycled.

The NTU project, for example, is one of two currently supported by the National Environment Agency’s (NEA) Closing the Waste Loop funding initiative.

The $45 million initiative was launched in 2017 to boost research and development in areas such as the recovery of materials from waste streams.

The other project, a recycling programme led by Singapore Polytechnic (SP), aims to recycle solar panels on a commercial scale and recover more than 90 per cent by weight of the materials from the solar panels, said NEA.

In 2019, The Straits Times reported that Sembcorp and SP will also work together to develop a pilot recycling plant for solar panels.

However, the institutions declined to comment when asked for updates on the effort.

Another research effort by NTU spin-off EtaVolt, a solar tech firm, is working with the university on various other solar recycling projects, said its co-founder and chief executive Stanley Wang.

The project is not funded by NEA’s Closing the Waste Loop initiative.

Dr Wang said that the upcoming projects aim to recover materials from decommissioned solar panels so they can be recycled and reutilised as raw materials for battery, solar panel manufacturing and other industrial applications.

“This would allow us to recover the end-of-life value of these raw materials, which can potentially be given back to companies in the form of rebates to incentivise them to recycle their solar panels sustainably,” he added.

 


 

Source The Straits Times